Dhanure, S. K.’s team published research in Oxidation Communications in 24 | CAS: 14807-75-1

Oxidation Communications published new progress about 14807-75-1. 14807-75-1 belongs to ethers-buliding-blocks, auxiliary class Salt,Thiourea,Amine,Aliphatic hydrocarbon chain, name is Formamidine disulfide dihydrochloride, and the molecular formula is C2H8Cl2N4S2, COA of Formula: C2H8Cl2N4S2.

Dhanure, S. K. published the artcileKinetics of oxidation of thiourea by chloramine-T and p-benzoquinone, COA of Formula: C2H8Cl2N4S2, the publication is Oxidation Communications (2001), 24(1), 91-98, database is CAplus.

The kinetics of oxidation of thiourea by chloramine-T both in acid and alk. medium was studied. In acid medium, the reaction is second order in substrate, first order in oxidant and inverse fractional order in H+. In alk. medium the reaction is first order in oxidant, first order in substrate and inverse fractional order in [OH]. Stoichiometric experiments reveal that these reactions are mixed: the first one being the formation of disulfide and the second one in a parallel sequence giving urea and sulfate ion. A mechanism is postulated to explain the results. As a parallel study 1,4-benzoquinone was used for the oxidation of thiourea. These reactions occur with facility at pH 3-5; they are very fast below pH 3. The oxidant benzoquinone undergoes decomposition in alk. medium ruling out the possibility of any oxidation of thiourea by benzoquinone in the alk. medium.

Oxidation Communications published new progress about 14807-75-1. 14807-75-1 belongs to ethers-buliding-blocks, auxiliary class Salt,Thiourea,Amine,Aliphatic hydrocarbon chain, name is Formamidine disulfide dihydrochloride, and the molecular formula is C2H8Cl2N4S2, COA of Formula: C2H8Cl2N4S2.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem