Dhanure, S. K.’s team published research in Oxidation Communications in 24 | CAS: 14807-75-1

Oxidation Communications published new progress about 14807-75-1. 14807-75-1 belongs to ethers-buliding-blocks, auxiliary class Salt,Thiourea,Amine,Aliphatic hydrocarbon chain, name is Formamidine disulfide dihydrochloride, and the molecular formula is C2H8Cl2N4S2, Computed Properties of 14807-75-1.

Dhanure, S. K. published the artcileKinetics of oxidation of thiourea by chloramine-T and p-benzoquinone, Computed Properties of 14807-75-1, the publication is Oxidation Communications (2001), 24(3), 400-407, database is CAplus.

Kinetics of oxidation of thiourea by chloramine-T both in acid and alk. medium was studied. In acid medium, the reaction is second order in substrate, first order in oxidant and inverse fractional order in [H+]. In alk. medium the reaction is first order in oxidant, substrate and inverse fractional order in [OH]. Stoichiometric experiments reveal that these oxidation reactions are mixed reactions: the first one being the formation of disulfide and the second one in a parallel sequence giving urea and sulfate ion. A mechanism is postulated to explain the results. As a parallel study 1,4-benzoquinone was used for the oxidation of thiourea. These reactions occur with facility at pH 3-5; they are very fast below pH 3. The oxidant benzoquinone undergoes decomposition in alk. medium ruling out the possibility of any oxidation by benzoquinone of thiourea in alk. medium.

Oxidation Communications published new progress about 14807-75-1. 14807-75-1 belongs to ethers-buliding-blocks, auxiliary class Salt,Thiourea,Amine,Aliphatic hydrocarbon chain, name is Formamidine disulfide dihydrochloride, and the molecular formula is C2H8Cl2N4S2, Computed Properties of 14807-75-1.

Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem