Furukawa, Takayuki published the artcileC-H Functionalization at Sterically Congested Positions by the Platinum-Catalyzed Borylation of Arenes, Synthetic Route of 596819-12-4, the publication is Journal of the American Chemical Society (2015), 137(38), 12211-12214, database is CAplus and MEDLINE.
Despite significant progress in the area of C-H bond functionalization of arenes, no general method is reported for the functionalization of C-H bonds at the sterically encumbered positions of simple arenes, such as mesitylene. Herein, the authors report the development of the 1st Pt-based catalyst for C-H borylation of arenes and heteroarenes. Notably, this method exhibited high tolerance toward steric hindrance and provided rapid access to 2,6-disubstituted phenylboronic esters, valuable building blocks for further elaborations.
Journal of the American Chemical Society published new progress about 596819-12-4. 596819-12-4 belongs to ethers-buliding-blocks, auxiliary class Thiophene,Boronic acid and ester,Ether,Boronate Esters,Boronic acid and ester, name is 2-(5-Methoxythiophen-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, and the molecular formula is C11H17BO3S, Synthetic Route of 596819-12-4.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem