Sahin, Neslihan published the artcileFirst used of Alkylbenzimidazole-Cobalt(II) complexes as a catalyst for the N-Alkylation of amines with alcohols under solvent-free medium, Related Products of ethers-buliding-blocks, the publication is Journal of Organometallic Chemistry (2020), 121285, database is CAplus.
Alkylbenzimidazole-cobalt(II) I [R = allyl, 2-methylallyl, 2-vinyloxyethyl]-catalyzed direct N-alkylation reactions of amines with alcs. derivatives was investigated under solvent-free medium. For this purpose, a series of cobalt(II) complexes I was synthesized and novel complexes fully characterized by elemental anal., FT-IR, 1H-NMR and 13C-NMR spectroscopies. Also, the structure of the complex I [R = allyl] was confirmed by X-ray crystallog. Generally, the N-alkylating reaction is usually performed in toluene with various metal complexes including cobalt. In this catalytic study of complexes I, was carried out without solvent and alc. acted both as solvent and reactant. Conversion and selectivity of amine products according to imine products for alkylation reactions were seen high yield in medium solvent-free relative to in toluene.
Journal of Organometallic Chemistry published new progress about 52818-63-0. 52818-63-0 belongs to ethers-buliding-blocks, auxiliary class Pyridine,Amine,Benzene,Ether, name is N-(4-Methoxybenzyl)pyridin-2-amine, and the molecular formula is C13H14N2O, Related Products of ethers-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Ether,
Ether | (C2H5)2O – PubChem