Kucuk, Asuman Celik published the artcileInfluence of LiBOB as an electrolyte additive on the performance of BiF3/C for fluoride shuttle batteries, HPLC of Formula: 143-24-8, the main research area is bismuth fluoride carbon film battery electrolyte ionic conductivity.
The potential effects of using lithium bis(oxalato)borate (LiBOB) as an electrolyte additive on the redox reactions of the pos. bismuth fluoride (BiF3) electrode were investigated in tetraglyme (G4) containing the anion acceptor (AA) triphenylboroxin (TPhBX). The electrolyte system, containing 0.06 M LiBOB, 0.5 M TPhBX, and saturated cesium fluoride (CsF) was prepared The study also included a comparison with previously studied systems based on G4, which did not contain LiBOB but AA. The tolerances to reduction and oxidation were enhanced after introducing LiBOB to the system. The capacity of BiF3 improved at C/10 rate. Defluorination of BiF3 was demonstrated to proceed through a direct desorption-insertion mechanism, whereas the contribution of the dissolution-deposition mechanism was known to be predominant in the G4-based systems. Addition of only 1 weight/weight% LiBOB to the G4 system resulted in an interesting change in the mechanism and an improvement in the capacity at high C rate. This improvement was associated with the increasing electrochem. stability of the electrolyte due to the interaction between BOB- and Cs+, reducing the possibilities of electrolyte degradation and loss of active material owing to a direct desorption-insertion mechanism.
Journal of the Electrochemical Society published new progress about Batteries. 143-24-8 belongs to class ethers-buliding-blocks, name is 2,5,8,11,14-Pentaoxapentadecane, and the molecular formula is C10H22O5, HPLC of Formula: 143-24-8.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem