Nickel-Catalyzed Reductive Bis-Allylation of Alkynes was written by Komeyama, Kimihiro;Yamahata, Yuta;Osaka, Itaru. And the article was included in Organic Letters in 2018.Synthetic Route of C6H10O2 This article mentions the following:
A reductive nickel-catalyzed bis-allylation of alkynes with allyl acetates has been developed, leading to 1,4,7-triene skeletons. This reductive bis-allylation proceeds under mild conditions and exhibits good functional group tolerance in both the allyl acetates and the alkynes. In the experiment, the researchers used many compounds, for example, 1,4-Dimethoxy-2-butyne (cas: 16356-02-8Synthetic Route of C6H10O2).
1,4-Dimethoxy-2-butyne (cas: 16356-02-8) belongs to ethers. Ether is less polar than esters, alcohols or amines because of the oxygen atom that is unable to participate in hydrogen bonding due to the presence of bulky alkyl groups on both sides of the oxygen atom. At room temperature, ethers are pleasant-smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for soil.Synthetic Route of C6H10O2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem