Gevorgyan, Ashot et al. published their research in Organic Chemistry Frontiers in 2017 | CAS: 5367-32-8

3-Methyl-4-nitroanisole (cas: 5367-32-8) belongs to ethers. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides. Ethers feature bent C–O–C linkages. In dimethyl ether, the bond angle is 111° and C–O distances are 141 pm. The barrier to rotation about the C–O bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.Computed Properties of C8H9NO3

Disilanes as oxygen scavengers and surrogates of hydrosilanes suitable for selective reduction of nitroarenes, phosphine oxides and other valuable substrates was written by Gevorgyan, Ashot;Mkrtchyan, Satenik;Grigoryan, Tatevik;Iaroshenko, Viktor O.. And the article was included in Organic Chemistry Frontiers in 2017.Computed Properties of C8H9NO3 This article mentions the following:

In this report, the reaction of nitroarenes RNO2 (R = Pr, cyclohexyl, 2-methylphenyl, pyridin-3-yl, etc.) with hexamethyldisilane under various conditions affords a different range of compounds with excellent selectivity. In particular, the reaction of nitroarenes with hexamethyldisilane using a CsF/TBAB/toluene system provides suitable azo compounds, while in the presence of a CsF/TBAB/[Pd]/EtOH system this hexamethyldisilane acts as a novel surrogate of gaseous trimethylsilane, thus, reducing nitroarenes to corresponding anilines RNH2. The synthetic value of the developed methodol. was further extended by the reduction of a wide range of substrates including N-oxides such as 2-methyl-quinoline-1-oxide, isoquinoline-2-oxide, 2,6-dimethylpyridine-1-oxide, 2-phenylpyridine-1-oxide, sulfoxides such as methanesulfinylbenzene, (benzenesulfinyl)benzene, 1-methanesulfinyl-4-methylbenzene, [(phenylmethane)sulfinylmethyl]benzene, phosphine oxides such as [[(diphenylphosphoroso)methyl](phenyl)phosphoryl]benzene, [[3-(diphenylphosphoroso)propyl](phenyl)phosphoryl]benzene, (diphenylphosphoryl)benzene, etc. In the experiment, the researchers used many compounds, for example, 3-Methyl-4-nitroanisole (cas: 5367-32-8Computed Properties of C8H9NO3).

3-Methyl-4-nitroanisole (cas: 5367-32-8) belongs to ethers. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides. Ethers feature bent C–O–C linkages. In dimethyl ether, the bond angle is 111° and C–O distances are 141 pm. The barrier to rotation about the C–O bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.Computed Properties of C8H9NO3

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem