Nickel-catalyzed denitrative etherification of activated nitrobenzenes was written by Zamiran, Fatemeh;Ghaderi, Arash. And the article was included in Journal of the Iranian Chemical Society in 2019.Application In Synthesis of 1-(4-(4-Methoxyphenoxy)phenyl)ethanone This article mentions the following:
Electron-deficient nitrobenzenes RC6H4NO2 [R = 4-CHO, 4-CN, 4-C(O)CH3, 2-CHO] were coupled with phenols/alcs. R1OH (R1 = Ph, CH3(CH2)3, naphth-2-yl, etc.) to form diaryl/alkyl aryl ethers RC6H4OR1 with the aid of NiCl2 as the catalyst. The reactions were conducted under ligand- and oxidant-free conditions without the exclusion of air or moisture. The initial studies on the mechanism of the reaction revealed two solvent-dependent approaches. In molten TBAB, the SNAr mechanism seems to predominate; while, in DMF, the reaction might include the radical species. In the experiment, the researchers used many compounds, for example, 1-(4-(4-Methoxyphenoxy)phenyl)ethanone (cas: 54916-28-8Application In Synthesis of 1-(4-(4-Methoxyphenoxy)phenyl)ethanone).
1-(4-(4-Methoxyphenoxy)phenyl)ethanone (cas: 54916-28-8) belongs to ethers. Of all the functional groups, ethers are the least reactive ones. Ether bonds are quite stable towards bases, oxidizing agents and reducing agents. But on the other hand, ethers undergo cleavage by reaction with acids. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as solvents and plasticizers.Application In Synthesis of 1-(4-(4-Methoxyphenoxy)phenyl)ethanone
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem