Synthetic Route of C10H20O5In 2019 ,《Tunable Reduction of 2,4,6-Tri(4-pyridyl)-1,3,5-Triazine: From Radical Anion to Diradical Dianion to Radical Metal-Organic Framework》 appeared in Angewandte Chemie, International Edition. The author of the article were Tang, Shuxuan; Ruan, Huapeng; Feng, Rui; Zhao, Yue; Tan, Gengwen; Zhang, Li; Wang, Xinping. The article conveys some information:
The reduction of 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPT) with alkali metals resulted in four radical anion salts (1, 2, 4 and 5) and one diradical dianion salt (3). Single-crystal x-ray diffraction and ESR spectroscopy reveal that 1 contains the monoradical anion TPT.- stacked in one-dimensional (1D) with K+(18c6) and 2 can be viewed as a 1D magnetic chain of TPT.-, while 4 and 5 form radical metal-organic frameworks (RMOFs). 1D pore passages, with a diameter of 6.0 Å, containing solvent mols. were observed in 5. Variable-temperature EPR measurements show that 3 has an open-shell singlet ground state that can be excited to a triplet state, consistent with theor. calculation The work suggests that the direct reduction approach could lead to the formation of RMOFs. The results came from multiple reactions, including the reaction of 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Synthetic Route of C10H20O5)
1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Synthetic Route of C10H20O5
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem