Application of 33100-27-5In 2020 ,《An electrospray ionization mass spectrometric study of beryllium chloride solutions and complexes with crown ether and cryptand macrocyclic ligands》 appeared in Journal of Coordination Chemistry. The author of the article were Raymond, Onyekachi; Henderson, William; Lane, Joseph R.; Brothers, Penelope J.; Plieger, Paul G.. The article conveys some information:
The speciation of beryllium chloride solutions was studied using electrospray ionization mass spectrometry in both pos. and neg. ion modes. The majority of observed species were mixed beryllium-chlorido-oxido-hydroxido species, with the degree of hydration of the observed ions depending on the number of chloride ions. The observed species contain between 1 and 6 Be ions. The interactions of BeCl2 with a selection of crown ether ligands and cryptand[2.2.2] were also studied using ESI MS. These ligands have low affinity for Be2+, instead the observed ions are dominated by species formed from adventitious Na+ or K+ ions. The crown ether 12-crown-4 showed the most complex spectra, as a result of greater interactions with Be2+, as evidenced by observed ions such as [BeX(12-crown-4)]+ (X = Cl or OH). The interactions of crown ethers with beryllium ions (as well as coordinated Cl- or OH- ancillary ligands) were studied using D. Functional Theory [B3LYP/6-311++G(dp)], where the species [BeX(crown ether)]+ (X = Cl or OH) are considerably more stable than [Be(crown ether)]2+ species, with 12-crown-4 forming the most stable complex. The combination of ESI MS and DFT studies indicates that full encapsulation of the Be2+ by crown ethers is unfavorable, and coordination with an accompanying hydroxide or chloride is preferred. The results came from multiple reactions, including the reaction of 1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5Application of 33100-27-5)
1,4,7,10,13-Pentaoxacyclopentadecane(cas: 33100-27-5) is a member of crown ether Ligands. Crown-ethers are macrocyclic polyethers capable of forming host-guest complexes, especially with inorganic and organic cations. Crown-ethers can incorporate protonated primary amine compounds by formation of ion-dipole bonds with the oxygen atoms of the chiral selector. Crown-ethers have been widely used for the separation of several pharmaceuticals both in aqueous and non-aqueous media. Application of 33100-27-5
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem