Related Products of 2235-01-0《A concise diastereoselective approach to (+)-dexoxadrol, (-)-epi-dexoxadrol, (-)-conhydrine and (+)-lentiginosine from (-)-pipecolinic acid》 was published in 2013. The authors were Bhat, Chinmay;Tilve, Santosh G., and the article was included in《Tetrahedron》. The author mentioned the following in the article:
A new diastereoselective pathway for the total synthesis of (+)-dexoxadrol (I), first asym. synthesis of (-)-epi-dexoxadrol (II) and formal synthesis of (-)-β- and (+)-α-conhydrine III (R = OH, R1 = H; R = H, R1 = OH, resp.) and (+)-lentiginosine (IV) is presented using com. available (-)-pipecolinic acid. The key reactions utilized are Sharpless asym. dihydroxylation and Wittig reaction. The paper further describes the study of the effect of protecting groups on dihydroxylation of a terminal olefin in piperidine ring system.Dimethoxydiphenylmethane (cas: 2235-01-0) were involved in the experimental procedure.
Dimethoxydiphenylmethane is one of ethers-buliding-blocks. Ethers feature bent C–O–C linkages. In dimethyl ether, the bond angle is 111° and C–O distances are 141 pm. The barrier to rotation about the C–O bonds is low. Related Products of 2235-01-0 The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3.
Reference:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem