Zhang, Liang; Li, Yafei; Wang, Li; Cao, Zhu; Zhang, Qian; Li, Yahong published the artcile< Two β-Diketiminate Zinc Complexes with 1-D Chain and Dinuclear Topologies: Synthesis, Structures, and Catalytic Behavior>, SDS of cas: 190788-60-4, the main research area is preparation zinc diketiminate complex borylation catalyst aryl iodide.
Two zinc complexes, [L1Zn2Et2]n (1) and [L2Zn2Et2] (2), were synthesized by reacting bis(β-diketiminate) ligands H2L1 and H2L2 with ZnEt2. X-ray single-crystal diffraction anal. indicated that compound 1 displays a novel 1-dimensional chain structure. Compound 2 is dinuclear. The two compounds were employed to catalyze the coupling reaction of aryl iodides with B2Pin2. They were both catalytically active toward this transformation. Compound 1 exhibited higher catalytic activity than that of complex 2. The borylation reactions catalyzed by 1 possess the features of milder conditions, high functional group tolerance and wide range of substrate scopes.
European Journal of Inorganic Chemistry published new progress about Aryl iodides Role: RCT (Reactant), RACT (Reactant or Reagent). 190788-60-4 belongs to class ethers-buliding-blocks, and the molecular formula is C13H19BO3, SDS of cas: 190788-60-4.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem