Varni, Anthony J.; Bautista, Michael V.; Noonan, Kevin J. T. published the artcile< Chemoselective Rhodium-Catalyzed Borylation of Bromoiodoarenes Under Mild Conditions>, Reference of 190788-60-4, the main research area is rhodium catalyst chemoselective borylation bromoiodoarene preparation bromoaryl boronate; aryl bromide boronate trifluoroborate preparation Suzuki coupling polymerization substrate.
A chemoselective rhodium-catalyzed borylation has been developed for the preparation of aryl boronate esters. The reaction proceeds under mild conditions with excellent selectivity for C-I bonds in bromoiodoarenes and exhibits broad functional group tolerance. This procedure can act as a complementary approach toward bifunctional arenes along with other metal-catalyzed borylations. Addnl., the reaction’s utility in the preparation of monomers for metal-catalyzed cross-coupling polymerization is demonstrated.
Journal of Organic Chemistry published new progress about Aryl iodides Role: RCT (Reactant), RACT (Reactant or Reagent). 190788-60-4 belongs to class ethers-buliding-blocks, and the molecular formula is C13H19BO3, Reference of 190788-60-4.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem