Wucher, Philipp’s team published research in ACS Catalysis in 2014-08-01 | 17100-64-0

ACS Catalysis published new progress about Crystal structure. 17100-64-0 belongs to class ethers-buliding-blocks, and the molecular formula is C8H9BrO2, Computed Properties of 17100-64-0.

Wucher, Philipp; Schwaderer, Judith B.; Mecking, Stefan published the artcile< Solid-Supported Single-Component Pd(II) Catalysts for Polar Monomer Insertion Copolymerization>, Computed Properties of 17100-64-0, the main research area is solid supported palladium catalyst preparation polar monomer insertion copolymerization; polystyrene supported methylpalladium sulfonatophenylphosphine complex preparation crystal mol structure; clay silica physisorbed methylpalladium sulfonatophenylphosphine complex preparation ethylene polymerization; montmorillonite clay supported methylpalladium sulfonatophenylphosphine complex preparation catalyst.

Heterogenized representatives of neutral phosphine sulfonato Pd(II) complexes for polar monomer insertion polymerization were prepared by two different approaches. [{κ2-(P,O)-(2-anisyl)2PC6H4SO2O}Pd(Me)L] (L = pyr, dmso, or Cl) complexes were physisorbed on inorganic substrates, namely, clay or silica. In addition, new phosphine sulfonato complexes bearing hydroxyl linker groups at the nonchelating P-aryl moiety were prepared These complexes were covalently tethered to cross-linked polystyrene. All immobilized palladium complexes are active in ethylene polymerization and ethylene/MA copolymerization without any addnl. cocatalyst. In addition, separation from the polymer solution formed and reutilization for another polymerization were demonstrated for polystyrene-bound complexes.

ACS Catalysis published new progress about Crystal structure. 17100-64-0 belongs to class ethers-buliding-blocks, and the molecular formula is C8H9BrO2, Computed Properties of 17100-64-0.

Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem