Application of 882-33-7In 2021 ,《Rhodium-Catalyzed Twofold Unsymmetrical C-H Alkenylation-Annulation/Thiolation Reaction To Access Thiobenzofurans》 was published in Organic Letters. The article was written by Lin, Jian; Hu, Liuyu; Chen, Chao; Feng, Huijin; Yu, Yang; Yang, Yaxi; Zhou, Bing. The article contains the following contents:
A Rh(III)-catalyzed twofold unsym. C-H alkenylation-annulation/thiolation reaction was developed, enabling the straightforward and efficient synthesis of various thiobenzofurans I [R1 = Me, Et, Ph, CH2CH2OBn; R2 = H, Me; R3 = n-Pr, Ph, 2-thienyl, etc.; R4 = H, OMe, F, OBn; R5 = H, Me, Br, etc.; R4R5 = OCH2O, OCH2CH2O] in one step. This robust protocol proceeded with a broad substrate scope and good functional group tolerance under relatively mild reaction conditions. In addition to this study using 1,2-Diphenyldisulfane, there are many other studies that have used 1,2-Diphenyldisulfane(cas: 882-33-7Application of 882-33-7) was used in this study.
1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers. Ethers lack the hydroxyl groups of alcohols. Without the strongly polarized O―H bond, ether molecules cannot engage in hydrogen bonding with each other. Application of 882-33-7
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem