Formula: C12H10S2In 2021 ,《Green Aerobic Oxidation of Thiols to Disulfides by Flavin-Iodine Coupled Organocatalysis》 was published in Synlett. The article was written by Oka, Marina; Kozako, Ryo; Iida, Hiroki. The article contains the following contents:
Coupled catalysis using a riboflavin-derived organocatalyst and mol. iodine successfully promoted the aerobic oxidation of thiols to disulfides under metal-free mild conditions. The activation of mol. oxygen occurred smoothly at room temperature through the transfer of electrons from the iodine catalyst to the biomimetic flavin catalyst, forming the basis for a green oxidative synthesis of disulfides from thiols. In addition to this study using 1,2-Diphenyldisulfane, there are many other studies that have used 1,2-Diphenyldisulfane(cas: 882-33-7Formula: C12H10S2) was used in this study.
1,2-Diphenyldisulfane(cas: 882-33-7) belongs to ethers.The C-O bonds that comprise simple ethers are strong. Formula: C12H10S2 They are unreactive toward all but the strongest bases. Although generally of low chemical reactivity, they are more reactive than alkanes.
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem