On July 19, 2019, Zhang, Shanshan; Chen, Fei; He, Yan-Mei; Fan, Qing-Hua published an article.Application In Synthesis of (2-Bromo-5-methoxyphenyl)methanamine The title of the article was Asymmetric Hydrogenation of Dibenzo[c,e]azepine Derivatives with Chiral Cationic Ruthenium Diamine Catalysts. And the article contained the following:
An efficient Ru-catalyzed asym. hydrogenation of dibenzo[c,e]azepines is reported. A series of seven-membered cyclic amines were obtained with moderate to excellent enantioselectivity. The catalyst counteranion played an important role in achieving high-level chiral induction. Moreover, a one-pot synthesis of chiral 6,7-dihydro-5H-dibenz[c,e]azepines via two-step reductive amination was also developed. The experimental process involved the reaction of (2-Bromo-5-methoxyphenyl)methanamine(cas: 887581-09-1).Application In Synthesis of (2-Bromo-5-methoxyphenyl)methanamine
The Article related to asym hydrogenation dibenzoazepine derivative ruthenium diamine catalyst, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Hydroxylamines, Hydrazines, Triazenes, Azides, Azines, and Azo and Diazo Compounds and other aspects.Application In Synthesis of (2-Bromo-5-methoxyphenyl)methanamine
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem