On February 21, 2014, Cheng, Chen; Hartwig, John F. published an article.Application of 1417036-28-2 The title of the article was Rhodium-Catalyzed Intermolecular C-H Silylation of Arenes with High Steric Regiocontrol. And the article contained the following:
Regioselective C-H functionalization of arenes has widespread applications in synthetic chem. The regioselectivity of these reactions is often controlled by directing groups or steric hindrance ortho to a potential reaction site. Here, authors report a catalytic intermol. C-H silylation of unactivated arenes that manifests very high regioselectivity through steric effects of substituents meta to a potential site of reactivity. The silyl moiety can be further functionalized under mild conditions but is also inert toward many common organic transformations, rendering the silylarene products useful building blocks. The remote steric effect that we observe results from the steric properties of both the rhodium catalyst and the silane. The experimental process involved the reaction of 2-(3-Methoxy-4-methylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(cas: 1417036-28-2).Application of 1417036-28-2
The Article related to rhodium catalyzed intermol carbon hydrogen silylation arene steric regiocontrol, Organometallic and Organometalloidal Compounds: Silicon Compounds and other aspects.Application of 1417036-28-2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem