On October 4, 2013, Ichiishi, Naoko; Canty, Allan J.; Yates, Brian F.; Sanford, Melanie S. published an article.Computed Properties of 321-28-8 The title of the article was Cu-Catalyzed Fluorination of Diaryliodonium Salts with KF. And the article contained the following:
A mild Cu-catalyzed nucleophilic fluorination of unsym. diaryliodonium salts with KF is described. This protocol preferentially fluorinates the smaller aromatic ligand on iodine(III). The reaction exhibits a broad substrate scope and proceeds with high chemoselectivity and functional group tolerance. E.g., in presence of Cu(OTf)2 and 18-crown-6, nucleophilic fluorination of diaryliodonium salt (I) with KF gave 85% II and mesityl fluoride (99:1). DFT calculations implicate a CuI/CuIII catalytic cycle. The experimental process involved the reaction of 1-Fluoro-2-methoxybenzene(cas: 321-28-8).Computed Properties of 321-28-8
The Article related to copper catalyst nucleophilic fluorination diaryliodonium salt potassium fluoride, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Halides and Halonium Compounds and other aspects.Computed Properties of 321-28-8
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