Unno, Masafumi; Tanaka, Ryoji; Obinata, Daisuke; Endo, Mayuko; Sakurai, Tomoyuki; Ojima, Satoshi; Katayama, Takako; Fugami, Keigo published an article in 2011, the title of the article was Solvent-free synthesis of siloxanes and their usage as potential cross-coupling reagents.Category: ethers-buliding-blocks And the article contains the following content:
Hexaarylcyclotrisiloxanes were selectively prepared by solvent-free synthesis from diarylsilanediol. These well-known stable compounds were found to undergo palladium-catalyzed cross-coupling reaction with aryl halides in good yields. All of attached aryl groups on silicon atom could be utilized. Furthermore, base-sensitive functionality such as acetyl and nitro groups survived the reaction. The experimental process involved the reaction of Benzyl(4-bromophenyl)sulfane(cas: 53136-21-3).Category: ethers-buliding-blocks
The Article related to hexaarylcyclotrisiloxane solvent free preparation cross coupling reaction aryl halide, biaryl preparation, Organometallic and Organometalloidal Compounds: Metal Heterocyclic Compounds and Cluster Compounds and other aspects.Category: ethers-buliding-blocks
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem