Villanueva, Omar; Weldy, Nina Mace; Blakey, Simon B.; MacBeth, Cora E. published an article in 2015, the title of the article was Cobalt catalyzed sp3 C-H amination utilizing aryl azides.Related Products of 157869-15-3 And the article contains the following content:
A dinuclear Co(II) complex supported by a modular, tunable redox-active ligand system is capable of selective C-H amination to form N-containing 5-, 6- and 7-membered heterocycles, I [R = H, Me; R1 = H, CF3, OMe; R2 = C6H5, 4-F3CC6H4, 4-H3COC6H4, 3-pyridinyl, 1-phenylsulfonyl-1H-indol-3-yl; X = (CH2)n; n = 1, 2, 3] and 5-methoxy-2-phenyl-1H-indole from aryl azides 2-N3-5-R1C6H3(CH2)nCH(R)(R2) in good yields at low (1 mol%) catalyst loading. The reaction is tolerant of medicinally relevant heterocycles. The synthetic versatility obtained using low loadings of an earth abundant transition metal complex represents a significant advance in catalytic C-H amination technol. The experimental process involved the reaction of 2-((4-Methoxyphenyl)ethynyl)aniline(cas: 157869-15-3).Related Products of 157869-15-3
The Article related to indoline preparation, azide aryl amination cobalt catalyst, Heterocyclic Compounds (One Hetero Atom): Indoles, Indolizines, Carbazoles, and Other Arenopyrroles and other aspects.Related Products of 157869-15-3
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem