On November 30, 2021, Wang, Dongdong; Gong, Wanbing; Zhang, Jifang; Han, Miaomiao; Chen, Chun; Zhang, Yunxia; Wang, Guozhong; Zhang, Haimin; Zhao, Huijun published an article.Name: 2-Methylanisole The title of the article was Encapsulated Ni-Co alloy nanoparticles as efficient catalyst for hydrodeoxygenation of biomass derivatives in water. And the article contained the following:
Catalytic hydrodeoxygenation (HDO) is one of the most promising strategies to transform oxygen-rich biomass derivatives into high value-added chems. and fuels, but highly challenging due to the lack of highly efficient nonprecious metal catalysts. Herein, we report for the first time of a facile synthetic approach to controllably fabricate well-defined Ni-Co alloy NPs confined on the tip of N-CNTs as HDO catalyst. The resultant Ni-Co alloy catalyst possesses outstanding HDO performance towards biomass-derived vanillin into 2-methoxy-4-methylphenol in water with 100% conversion efficiency and selectivity under mild reaction conditions, surpassing the reported high performance nonprecious HDO catalysts. Impressively, our exptl. results also unveil that the Ni-Co alloy catalyst can be generically applied to catalyze HDO of vanillin derivatives and other aromatic aldehydes in water with 100% conversion efficiency and over 90% selectivity. Importantly, our DFT calculations and exptl. results confirm that the achieved outstanding HDO catalytic performance is due to the greatly promoted selective adsorption and activation of C=O, and desorption of the activated hydrogen species by the synergism of the alloyed Ni-Co NPs. The findings of this work affords a new strategy to design and develop efficient transition metal-based catalysts for HDO reactions in water. The experimental process involved the reaction of 2-Methylanisole(cas: 578-58-5).Name: 2-Methylanisole
The Article related to nickel cobalt alloy nanoparticle water biomass catalytic hydrodeoxygenation, Placeholder for records without volume info and other aspects.Name: 2-Methylanisole
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem