Improved oxidative cleavage of lignin model compound by ORR in protic ionic liquid was written by Jiang, Haomin;Wang, Lei;Qiao, Lingling;Xue, Aiguo;Cheng, Yujuan;Chen, Yueying;Ren, Yuan;Chen, Yongmei;Wan, Pingyu. And the article was included in International Journal of Electrochemical Science in 2019.Application of 103-16-2 The following contents are mentioned in the article:
The electrochem. degradation of p-benzyloxyl phenol (PBP) in [HNEt3][HSO4] is investigated using an oxygen reductive reaction (ORR) cathode in a non-membrane cell. It is disclosed that the two-electron reductive products of O2 (that is H2O2) is the main reactive oxygen species (ROS) in [HNEt3][HSO4], a protic ionic liquid (PIL). The degradation of PBP in PIL with the degradation rate of 48.2% and the current efficiency of 29.5% are obtained, which is higher than that in [BMIM][BF4], an aprotic ionic liquid (AIL). Based on the products identified by GC-MS, the effect of electro-generated H2O2 on the cleavage of ether bond in PBP is proposed. The result confirms that the appropriate number of protons in supporting electrolyte plays an important role in electrochem. degradation of lignin model compounds This study involved multiple reactions and reactants, such as 4-Benzyloxyphenol (cas: 103-16-2Application of 103-16-2).
4-Benzyloxyphenol (cas: 103-16-2) belongs to ethers. Volatile esters with characteristic odours are used in synthetic flavours, perfumes, and cosmetics. Certain volatile esters are used as solvents for lacquers, paints, and varnishes. Because of their lack of hydrogen-bond-donating ability, esters do not self-associate. Consequently, esters are more volatile than carboxylic acids of similar molecular weight.Application of 103-16-2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem