Polyphosphazenes with Novel Architectures: Influence on Physical Properties and Behavior as Solid Polymer Electrolytes was written by Allcock, Harry R.;Sunderland, Nicolas J.;Ravikiran, Ramakrishna;Nelson, James M.. And the article was included in Macromolecules in 1998.Formula: C11H22O5 This article mentions the following:
Three types of polyphosphazenes with different architectures have been synthesized and characterized. The influence of the polymer architecture on solid ionic conductivity was of particular interest. The first type includes linear oligo- and polyphosphazenes with the general formula [N:P(OCH2CH2OCH2CH2OCH3)2]n (MEEP) with different chain lengths. The second type consists of a series of tri-armed star-branched polyphosphazenes with the general formula N{CH2CH2NH(CF3CH2O)2P[N:P(OCH2CH2OCH2CH2OCH3)2]n}3 with different arm lengths. These were synthesized via the reaction of the tridentate initiator [N{CH2CH2NH(CF3CH2O)2P:N-PCl3+}3][PCl6–]3 with the phosphoranimine Cl3P:NSiMe3 in CH2Cl2 followed by halogen replacement with sodium (methoxyethoxy)ethoxide. The mol. weights in this system were carefully controlled by variation of the monomer-to-initiator ratios, and the effect of polymer mol. weight on solid ionic conductivity was examined The third polymer system was designed to examine the effect of complex branching on ionic conductivity Thus, a highly branched polymer containing five branches from a cyclotriphosphazene pendent side group (with 26 ethyleneoxy units per repeat unit) was synthesized. The conductivity of this polymer in the presence of three different salts has been measured and compared to the behavior of MEEP with a corresponding mol. weight The mechanism of ion transport in these systems is discussed. In the experiment, the researchers used many compounds, for example, 2-(2-(2-((Tetrahydro-2H-pyran-2-yl)oxy)ethoxy)ethoxy)ethan-1-ol (cas: 60221-37-6Formula: C11H22O5).
2-(2-(2-((Tetrahydro-2H-pyran-2-yl)oxy)ethoxy)ethoxy)ethan-1-ol (cas: 60221-37-6) belongs to ethers. The oxygen atom in ethers are more electronegative than carbon, thus the hydrogens which are alpha to the ethers are more acidic than the simple hydrocarbons. Ethers can form hydrogen bonds with other molecules (alcohols, amines, etc.) that have O閳ユ椊 or N閳ユ椊 bonds. The ability to form hydrogen bonds with other compounds makes ethers particularly good solvents for a wide variety of organic compounds and a surprisingly large number of inorganic compounds.Formula: C11H22O5
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem