Solvent-free iodination of arenes at room temperature was written by Alexander, Varughese M.;Khandekar, Amit C.;Samant, Shriniwas D.. And the article was included in Synlett in 2003.Related Products of 75581-11-2 This article mentions the following:
Silica supported bismuth(III)nitrate pentahydrate (BNP-SiO2) was prepared under simple co-grinding condition. The iodination of aromatic compounds using BNP-SiO2 and mol. iodine under solvent-free conditions is described. The reaction occurred in the solid state at room temperature, yielding the corresponding mono-iodo derivative in good yields. However, less activated aromatics required longer reaction time with comparatively less yield. In the experiment, the researchers used many compounds, for example, 4-Iodo-1-methoxy-2-methylbenzene (cas: 75581-11-2Related Products of 75581-11-2).
4-Iodo-1-methoxy-2-methylbenzene (cas: 75581-11-2) belongs to ethers. Ethers are good solvents partly because they are not very reactive. Most ethers can be cleaved, however, by hydrobromic acid (HBr) to give alkyl bromides or by hydroiodic acid (HI) to give alkyl iodides. Ethers can form hydrogen bonds with other molecules (alcohols, amines, etc.) that have O―H or N―H bonds. The ability to form hydrogen bonds with other compounds makes ethers particularly good solvents for a wide variety of organic compounds and a surprisingly large number of inorganic compounds.Related Products of 75581-11-2
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem