《Nickel-Catalyzed Carbon-Sulfur Bond Formation through Couplings of Aryl Iodides and Aryl Ethanethioates》 was published in ChemistrySelect in 2020. These research results belong to Mao, Pu; Sui, Hong-Da; Yuan, Jin-Wei; Xiao, Yong-Mei; Yang, Liang-Ru; Mai, Wen-Peng. Electric Literature of C7H7IO The article mentions the following:
A nickel-catalyzed reductive coupling between aryl iodides 2-R-3-R1-4-R2-C6H2I (R = H, OMe, Cl; R1 = H, Me; R2 = H, F, CF3, Ph, etc.) and aryl ethanethioates 3-R3-4-R4-C6H3XC(O)R5 (X = S, O; R3 = H, F; R4 = H, Me, Cl, OMe, OCF3; R5 = Me, Ph, 2,2,2-trifluoroethyl, 3,3,3-trifluoropropyl) has been developed to afford diaryl sulfides 2-R-3-R1-4-R2-C6H2SC6H3-3-R3-4-R4. This method provides a novel and practical route to aryl thioetherification and can be effectively applied to electronically diverse aryl iodides without expensive metals such as palladium and ruthenium. In the experiment, the researchers used 1-Iodo-2-methoxybenzene(cas: 529-28-2Electric Literature of C7H7IO)
1-Iodo-2-methoxybenzene(cas: 529-28-2) participates in palladium catalyzed enantioselective Heck arylation of 2,3-dihydrofuran in the presence of chiral ionic liquids containing L-prolinate and L-lactate anions and non-chiral quaternary ammonium cations.Electric Literature of C7H7IO
Referemce:
Ether – Wikipedia,
Ether | (C2H5)2O – PubChem